Please use this identifier to cite or link to this item: http://dl.pgu.ac.ir/handle/Hannan/66360
Title: The activation and fixation of dinitrogen by iron phosphine complexes
Issue Date: Jan-2017
Publisher: Imperial College London;Chemistry
Description: Dinitrogen gas is the source of all biologically and industrially fixed nitrogen, yet the activation of this highly unreactive molecule is a significant challenge in modern chemistry. The current industrial route to fixed nitrogen compounds is the Haber-Bosch process, a reaction which has remained largely unaltered since the early 20th century. The catalytic fixation of N2 by molecular Fe complexes, by contrast, is a young and rapidly developing field, yet thus far few complexes can effect this transformation. This thesis explores the reactivity of electron-rich Fe phosphine complexes as potential catalysts for this transformation.;Open Access
Other Identifiers: http://hdl.handle.net/10044/1/45533
Type Of Material: OTHER
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Appears in Collections:Chemistry

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