جهت دسترسی به کاربرگه ی زیر، از این لینک استفاده کنید. http://dl.pgu.ac.ir/handle/Hannan/65626
Title: Electronic structures of cyclometalated palladium complexes in the higher oxidation states
Keywords: Science & Technology;Physical Sciences;Chemistry, Inorganic & Nuclear;Chemistry;C-H BONDS;FUNCTIONALIZATION;CATALYSIS;CHEMISTRY;LIGANDS;Inorganic & Nuclear Chemistry;0302 Inorganic Chemistry;0399 Other Chemical Sciences
Issue Date: 7-Oct-2016
Publisher: Royal Society of Chemistry
place: Engineering & Physical Science Research Council (EPSRC);Engineering & Physical Science Research Council (EPSRC)
Description: The electronic and redox properties of a series of cyclometalated Pd complexes with oxidation states of +2, +3 and +4 were examined using a range of currently available spectroscopic and electrochemical techniques. Changes in metal–ligand bond lengths were established by X-ray crystallography and correctly predicted by DFT calculations, from which the frontier orbitals and partial atomic charges can be obtained. X-ray absorption spectroscopy (XAS) revealed interesting XANES features that suggest a synergistic relationship between metal–ligand interactions. The electrochemical study of the Pd(II) dimer was found to contain two sequential oxidative potentials indicative of a weak metal–metal interaction.
URI: http://dx.doi.org/10.1039/c5dt02104a
Other Identifiers: 1477-9226
http://hdl.handle.net/10044/1/41204
EP/G070172/1
EP/K039946/1
Type Of Material: Other
Appears in Collections:Chemistry

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