جهت دسترسی به کاربرگه ی زیر، از این لینک استفاده کنید. http://dl.pgu.ac.ir/handle/10722/70101
Title: Asymmetric total synthesis of (-)-indicol by a carbene cyclization- cycloaddition cascade strategy
Keywords: Cascade reactions;Rhodium;Total synthesis;Indicol;Methane - analogs and derivatives - chemistry;Catalysis;Ruthenium - chemistry;Diterpenes - chemical synthesis - chemistry;Cyclization
Publisher: Wiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistry;Germany
Description: The first total synthesis of a secodolastane, (-)-indicol, has been accomplished. The key reaction is a rhodium(II)-mediated carbene cyclization-cycloaddition cascade, by which the core bicyclo[5.4.0]undecane skeleton was assembled. In this one-pot reaction, a domino series of transformations resulting in the construction of three o bonds and three stereocenters was realized in good yield. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.;link_to_subscribed_fulltext
Other Identifiers: Chemistry - A European Journal, 2007, v. 13 n. 34, p. 9589-9599
10.1002/chem.200700838
9599
172826
WOS:000251391000017
0947-6539
34
http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0947-6539&volume=13&issue=34&spage=9589&epage=9599&date=2007&atitle=Asymmetric+total+synthesis+of+(-)-indicol+by+a+carbene+cyclization-+cycloaddition+cascade+strategy
17763492
eid_2-s2.0-36749094079
9589
http://hdl.handle.net/10722/70101
13
Type Of Material: Article
Appears in Collections:Department of Chemistry

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