جهت دسترسی به کاربرگه ی زیر، از این لینک استفاده کنید. http://dl.pgu.ac.ir/handle/10722/69862
Title: Pd(II)/tbu-quinolineoxazoline: An Air-stable And Modular Chiral Catalyst System For Enantioselective Oxidative Cascade Cyclization
Keywords: Organometallic Compounds - chemistry;Cyclization;Catalysis;Palladium - chemistry;Heterocyclic Compounds with 4 or More Rings - chemical synthesis - chemistry
Publisher: American Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.html;United States
Description: An air-stable and structurally tunable chiral (t)Bu-quinolineoxazoline/Pd(II) catalyst system has been developed for the enantioselective oxidative cascade cyclization of a variety of disubstituted olefinic substrates, with the apparent advantages of good yields and excellent enantioselectivities (up to 98% ee) and diastereoselectivities (dr >24:1). A transition-state model has also been proposed to account for the excellent stereocontrol.;link_to_subscribed_fulltext
Other Identifiers: Organic Letters, 2009, v. 11 n. 24, p. 5626-5628
10.1021/ol902348t
5628
169782
WOS:000272461800015
1523-7060
24
19905004
5626
http://hdl.handle.net/10722/69862
11
Type Of Material: Article
Appears in Collections:Department of Chemistry

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