جهت دسترسی به کاربرگه ی زیر، از این لینک استفاده کنید. http://dl.pgu.ac.ir/handle/10722/135046
Title: Practical manganese-catalysed highly enantioselective cis-dihydroxylation of electron-deficient alkenes and detection of a cis-dioxomanganese(v) intermediate by high resolution ESI-MS analysis
Keywords: Electrons;Hydroxylation;Manganese;Catalysis;Alkenes
Publisher: Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp;United Kingdom
Description: A practical protocol has been developed for asymmetric cis-dihydroxylation of electron-deficient alkenes with Oxone catalysed by a manganese complex bearing a chiral tetradentate N 4-donor ligand affording cis-diols in up to 95% yield with up to 96% ee. Analysis of the reaction mixture by high resolution ESI-MS revealed the formation of a cis-dioxomanganese(v) intermediate. © 2011 The Royal Society of Chemistry.;link_to_subscribed_fulltext
Other Identifiers: Chemical Communications, 2011, v. 47 n. 40, p. 11204-11206
10.1039/c1cc11999k
11206
188055
WOS:000295483800003
1359-7345
40
http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1359-7345&volume=47&spage=&epage=&date=2011&atitle=Practical+manganese-catalysed+highly+enantioselective+cis-dihydroxylation+of+electron-deficient+alkenes+and+detection+of+a+cis-dioxomanganese(v)+intermediate+by+high+resolution+ESI-MS+analysis
21614373
eid_2-s2.0-80053501132
11204
http://hdl.handle.net/10722/135046
47
Type Of Material: Article
Appears in Collections:Department of Chemistry

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