Please use this identifier to cite or link to this item:
Title: 2-Arylacetic anhydrides as ammonium enolate precursors
Keywords: Dynamic Kinetic Resolution;Tricyclic-Beta-Lactones;Acyl Transfer Catalyst;Silyl Ketene Acetals;Asymmetric Organocatalysis;Enantioselective Synthesis;Carboxylic Anhydrides;Gamma-Butyrolactones;C-Acylation;Keto Acids;QD Chemistry;QD
Issue Date: 28-Jan-2014
Description: This work is supported by funding from the Carnegie Trust for the Universities of Scotland and EPSRC;Readily prepared 2-arylacetic anhydrides act as convenient ammonium enolate precursors in isothiourea (HBTM-2.1)-mediated catalytic asymmetric intermolecular Michael addition-lactonisation processes, giving diverse synthetic building blocks in good yield with high diastereo- and enantiocontrol (up to 98 : 2 dr and > 99% ee).;Postprint;Peer reviewed
Other Identifiers: Morrill , L C , Ledingham , L A , Couturier , J-P , Bickel , J , Harper , A D , Fallan , C & Smith , A D 2014 , ' 2-Arylacetic anhydrides as ammonium enolate precursors ' Organic & Biomolecular Chemistry , vol 12 , no. 4 , pp. 624-636 . DOI: 10.1039/c3ob41869c
PURE: 112004851
PURE UUID: 8fd17324-a3ad-4a21-b6d5-bf4d18f36a1d
WOS: 000330082700011
Type Of Material: OTHER
Appears in Collections:Chemistry (School of)

Files in This Item:
Click on the URI links for accessing contents.

Items in HannanDL are protected by copyright, with all rights reserved, unless otherwise indicated.