جهت دسترسی به کاربرگه ی زیر، از این لینک استفاده کنید. http://dl.pgu.ac.ir/handle/10023/1685
Title: Synthesis and stereochemical assignment of (+)-chamuvarinin
Keywords: Hydrolytic kinetic resolution;Annonaceous acetogenins;Uvaria-chamae;Stereoisomer library;Recent progress;Mosher method;Bearing;Condensation;Mechanisms;Murisolins;QD Chemistry;QD
Issue Date: 4-Feb-2011
Description: Supported by grants from EPSRC (EP/F011458/1) and The Wellcome Trust (086658).;A stereocontrolled total synthesis of (+)-chamuvarinin, isolated from the root extract of Uvaria Chamae, utilizes a convergent modular strategy to construct the adjacently linked C15−C28 ether array, followed by a late-stage Julia−Kocienski olefination to append the butenolide motif. This constitutes the first total synthesis of (+)-chamuvarinin, defining the relative and absolute configuration of this unique annonaceous acetogenin.;Publisher PDF;Peer reviewed
URI: http://dx.doi.org/10.1021/ol1028699
Other Identifiers: Florence , G J , Morris , J C , Murray , R G , Osler , J , Vanga , R R & Smith , T K 2011 , ' Synthesis and stereochemical assignment of (+)-chamuvarinin ' Organic Letters , vol 13 , no. 3 , pp. 514-517 . DOI: 10.1021/ol1028699
1523-7060
PURE: 5052033
PURE UUID: 8d348877-33dc-41b5-915c-5fa5833e5783
Type Of Material: OTHER
Appears in Collections:Chemistry (School of)

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